The network EUROMAP will contribute to the
development in the field of efficient, low cost organic photovoltaic elements
with conjugated polymers possessing semiconducting properties as an absorber.
The inherent advantage of using conjugated polymers for organic
photovoltaic devices is based on the possibility
to use well developed polymer processing technologies.
Therefore in this project it is proposed a new approach for solar cells fabrication,
in which the role of the photoactive layer will be played by a low bandgap
polymer i.e. a conjugated polymer with a bandgap around 1.5eV.
The utilisation of conjugated polymers in the solar cell's
active layer is based on the phenomenon of photoinduced electron transfer
first discovered in the polymer/ fullerene composites. Most of the activities
in the field after this discovery are devoted to the wide-gap polymers, mainly
poly-(phenylene-vinylene) PPV with the semiconducting gap of about 2.5eV
and C60 as an acceptor molecule. Typical values of power efficiency achieved
are about 1%. Basic principles of photovoltaics, however, require a better
matching of optical gap of the absorbers used in the cell to the solar irradiation
spectrum (A 1.5 spectrum). This means that the semiconductors with the gap
around 1.5eV can deliver higher energy conversion efficiencies.
The production of a cost efficient photovoltaic elements is
expected to have a major impact on the socio-economic environment due to
CO2 reduction. Further, a promising class of electroactive working materials
will be investigated within this project and will contribute to the technological
development of novel devices.
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DOC/POST doc positions